MILD HYDROCRACKING — A STATE OF THE ART

ABSTRACT

This paper is a brief, but not exhaustive review of the literature of the catalytic mild hydrocracking processes. It includes data characterizing reactivities, reaction network and kinetics of mild hydrocracking reactions. This review is designed for use as a reference for further research and development work in the field of mild hydrocracking.     

A PROCEDURE FOR THE PRODUCTION OF ULTRA-PURE PRECURSORS FROM COAL FOR THE MANUFACTURE OF VALUE-ADDED CARBON PRODUCTS - TREATMENT OF THE RESIDUE

ABSTRACT

Solvent extraction of coal results in a coal-derived extract containing the solvent-soluble organic portion of coal free of almost all mineral matter. A residue is also produced and consists of most of the mineral matter. Although a procedure has been developed to manufacture ultra-pure coke precursors for value-added carbon products from coal-derived extracts, treatment/rc-usc of the residue is necessary to make the process economically attractive and environmentally friendly. In this study, a technique has been developed to beneficiate the residue by specific gravity fractionation. It is found that nearly 70 % of the residue can be separated into a fraction containing less than 3.5% ash for a typical WV bituminous coal using an organic liquid having a specific gravity of 1.5. This treatment enables the residue to serve as a low-ash boiler fuel or a suitable precursor for the manufacture of materials such as activated carbons. Consequently, the potential for coal-derived precursors leading to new and non-conventionai marketable carbon products can be realized easily.     

Corrosion in Propane Deasphalting Unit in a Lube Producing Refinery: A Case Study

Abstract

Propane deasphalting is a process of recovery of hydrocarbon distillates from vacuum residue by extracting with liquid propane. A plated tower is used to carry out extraction where extract containing the deasphalted oil and raffinate containing the asphalt are separated. Extract and raffinates are then subject to propane recovery sections wherefrom propane is recovered and reused in extraction. Complete recovery of propane from deasphalted oil is carried out by flashing alone, but recovery from asphalt requires heating in a furnace followed by flashing. Severe corrosion has been observed in the propane condensers, coolers, and the overhead lines of the flashers and stripper columns. Studies have indicated that cracking of asphalt at the prevailing operating temperature and pressure, generating hydrogen sulfide, was the sole reason for corrosion. The problem has been minimized by adjusting the temperature and pressure without affecting the propane recovery efficiency.     

Effect of process parameters on the cutting quality in lasox cutting of mild steel

Samples of mild steel have been cut on a CO₂ laser machine using the principle of laser assisted oxygen cutting (LASOX). The combined effects of input process parameters (cutting speed, gas pressure, laser power and stand off distance) on cut quality (heat affected zone (HAZ) width, kerf width and surface roughness) have been studied. Regression analysis has been used to develop models that describe the effect of the independent process parameters on cut quality. Using the developed model, we attempted to optimize the input parameters that would improve the cut quality (minimization of HAZ width, kerf width and surface roughness), increase the productivity and minimize the total operation cost. We found from the study that the gas pressure and cutting speed had pronounced effect on cut quality. Low gas pressure produces lower HAZ width, lower kerf width and good surface finish whereas increase in speed results in higher HAZ width, lower kerf width and good surface finish.     

Linear and nonlinear optical properties of ZnGeP2 crystal for infrared laser device applications: revisited

Measurement of refractive indices in the spectral bands 9-11 microm and 1.32 microm from a cw CO2 laser and a Q-switched Nd:YAG laser, respectively, is reported in a ZnGeP2 crystal. A new set of Sellmeier dispersion relations has been derived from the measured refractive indices data in this crystal. Second-harmonic generation (SHG) of CO2 laser radiation in this crystal is also reported. It is also seen that the previously reported phase-matching data for others experiments in SHG and optical parametric devices is explained satisfactorily with this new set of Sellmeier dispersion relation.     

Photoresist application for the LIGA process

 Fabrication of high aspect ratio structures requires the use of a photoresist able to form a mold with vertical sidewalls. Thus the photoresist should have a high selectivity between the exposed and the unexposed area in the developer. It should be relatively free from stress when applied in thick layers necessary to make high aspect ratio structures. PMMA (Poly Methyl Methacrylate) is the photoresist of choice in the LIGA process, mainly for its ability to hold vertical sidewalls for tall structures. It is applied to the substrate by a glue-down process in which a pre-cast, high molecular weight, sheet of PMMA is attached to the plating base on a substrate. The applied photoresist is then milled down to the precise height by a fly-cutter prior to pattern transfer by x-ray exposure. The requirement that the applied layer be relatively free from stress dictates the choice of glue-down over casting. The substrate preparation steps, as well as the conditioning of the PMMA sheet prior to the glue-down, are done, in part, to reduce the stress in the glued down sheet of photoresist. The cutting of the PMMA sheet in the fly-cutter requires specific operating conditions as well as particular cutting tools to avoid introducing any stress and the resultant crazing of the photoresist. Received: 25 August 1997/Accepted: 3 September 1997     

On scheduling atomic and composite continuous media objects

In multiuser multimedia information systems (e.g., movie-on-demand, digital-editing), scheduling the retrievals of continuous media objects becomes a challenging task. This is because of both intra and inter lobject time dependencies. Intraobject time dependency refers to the real-time display requirement of a continuous media object. Interobject time dependency is the temporal relationships defined among multiple continuous media objects. In order to compose tailored multimedia presentations, a user might define complex time dependencies among multiple continuous media objects with various lengths and display bandwidths. Scheduling the retrieval tasks corresponding to the components of such a presentation in order to respect both inter and intra task time dependencies is the focus of this study. To tackle this task scheduling problem (CRS), we start with a simpler scheduling problem (ARS) where there is no inter task time dependency (e.g., movie-on-demand). Next, we investigate an augmented version of ARS (termed ARS⁺) where requests reserve displays in advance (e.g., reservation-based movie-on-demand). Finally, we extend our techniques proposed for ARS and ARS⁺ to address the CRS problem. We also provide formal definition of these scheduling problems and proof of their NP-hardness     

Index selection for databases: a hardness study and a principled heuristic solution

We study the index selection problem: Given a workload consisting of SQL statements on a database, and a user-specified storage constraint, recommend a set of indexes that have the maximum benefit for the given workload. We present a formal statement for this problem and show that it is computationally "hard" to solve or even approximate it. We develop a new algorithm for the problem which is based on treating the problem as a knapsack problem. The novelty of our approach lies in an LP (linear programming) based method that assigns benefits to individual indexes. For a slightly modified algorithm, that does more work, we prove that we can give instance specific guarantees about the quality of our solution. We conduct an extensive experimental evaluation of this new heuristic and compare it with previous solutions. Our results demonstrate that our solution is more scalable while achieving comparable quality.